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Polar covalent bonds have an unequal distribution of electron density, while nonpolar covalent bonds have equal distribution.
In a covalent bond, atoms share electrons to achieve a stable electron configuration. However, the way these electrons are shared can vary, leading to the formation of either polar or nonpolar covalent bonds.
In a polar covalent bond, the electrons are not shared equally between the two atoms. This is because one atom has a higher electronegativity, meaning it has a stronger pull on the shared electrons. This results in an unequal distribution of electron density, with a partial negative charge on the more electronegative atom and a partial positive charge on the less electronegative atom. This charge difference creates a dipole, or a separation of charges, within the molecule. Water (H2O) is a classic example of a molecule with polar covalent bonds.
On the other hand, in a nonpolar covalent bond, the electrons are shared equally between the two atoms. This happens when the atoms have the same or very similar electronegativities, so neither atom can pull the electrons closer to itself. This results in an equal distribution of electron density, with no charge difference or dipole within the molecule. An example of a molecule with nonpolar covalent bonds is methane (CH4).
In summary, the difference between polar and nonpolar covalent bonds lies in the distribution of electron density. This is determined by the relative electronegativities of the atoms involved in the bond. Understanding this difference is crucial in predicting the properties and behaviours of different molecules.
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