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Metallic bonding contributes to metal malleability by allowing metal atoms to slide over each other without breaking their bonds.
In more detail, metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons and positively charged metal ions. It is the main type of bonding that occurs in metallic materials and gives them their unique properties, such as malleability.
Malleability refers to the ability of a substance to be hammered or rolled into thin sheets without breaking. In metals, this is possible due to the nature of metallic bonding. The metal ions in a metallic bond are arranged in a closely packed lattice structure, surrounded by a 'sea' of delocalised electrons. These electrons are not associated with any particular ion and are free to move throughout the structure.
When a force is applied to a metal, the layers of ions can slide over each other. The delocalised electrons can easily adjust their positions to accommodate this movement. This means that the metallic bonds are not broken, but simply rearranged. This ability to rearrange without breaking is what gives metals their malleability.
Furthermore, the strength of the metallic bond also plays a role in a metal's malleability. Stronger bonds result in harder metals that are less malleable, while weaker bonds result in softer, more malleable metals. This is why different metals have different degrees of malleability. For example, gold is more malleable than iron because it has weaker metallic bonds.
In summary, the unique structure and properties of metallic bonding, particularly the presence of delocalised electrons and the ability of ions to slide over each other, are what allow metals to be malleable.
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