Need help from an expert?
The world’s top online tutoring provider trusted by students, parents, and schools globally.
Branched chain hydrocarbons are named using the IUPAC system, which includes the parent chain, substituents, and their positions.
The International Union of Pure and Applied Chemistry (IUPAC) has established a set of rules for naming branched chain hydrocarbons. The first step is to identify the longest continuous chain of carbon atoms, known as the parent chain. This chain is named according to the number of carbon atoms it contains, using prefixes such as 'meth-' for one carbon, 'eth-' for two, 'prop-' for three, and so on.
Next, you need to identify any branches or substituents, which are smaller chains of carbon atoms attached to the parent chain. These are named using similar prefixes, but end in '-yl' instead of '-ane'. For example, a branch with one carbon atom is a 'methyl' group, while a branch with two carbon atoms is an 'ethyl' group.
The position of each substituent on the parent chain is indicated by a number. You should number the carbon atoms in the parent chain starting from the end closest to the first substituent. If there are multiple substituents of the same type, you use prefixes such as 'di-', 'tri-', 'tetra-', etc., to indicate how many there are.
Finally, when writing the full name of the hydrocarbon, you list the substituents in alphabetical order before the name of the parent chain, with their positions separated by commas and the different parts of the name separated by hyphens. For example, a molecule with a three-carbon parent chain and a one-carbon branch on the second carbon would be named '2-methylpropane'.
Remember, the goal is to provide a unique and unambiguous name for each different hydrocarbon, so that anyone else can recreate the same molecule based on its name alone.
Study and Practice for Free
Trusted by 100,000+ Students Worldwide
Achieve Top Grades in your Exams with our Free Resources.
Practice Questions, Study Notes, and Past Exam Papers for all Subjects!
The world’s top online tutoring provider trusted by students, parents, and schools globally.