Question 1
Which type of bond is formed by the head-on overlap of atomic orbitals?
A. Pi bond
B. Sigma bond
C. Delta bond
D. Phi bond
Question 2
Which molecule contains resonance structures?
A. CH4
B. H2O
C. O3
D. N2
Question 3
In a pi bond, the overlapping of orbitals occurs:
A. Head-on
B. Sideways
C. Diagonally
D. Perpendicular
Question 4
Which of the following is NOT a property of sigma bonds?
A. Formed by head-on overlap
B. Stronger than pi bonds
C. Contains two regions of electron density
D. Allows free rotation of bonded atoms
Question 5
The concept of formal charge is used to:
A. Determine the charge on an ion
B. Predict the magnetic properties of a molecule
C. Assess the distribution of electrons in a molecule
D. Measure the bond strength
Question 6
a) Explain the difference between sigma (σ) and pi (π) bonds in terms of their formation and spatial orientation. [3]
b) Given a molecule with a double bond, how many sigma and pi bonds would it contain? Justify your answer. [2]
Question 7
a) What is the significance of formal charge in determining the most plausible Lewis structure for a molecule? [3]
b) For the molecule CO3^2-, calculate the formal charge on the central carbon atom. [2]
Question 8
a) Define resonance structures and explain their importance in understanding the structure of molecules. [3]
b) For the molecule SO3, draw two possible resonance structures. [2]
Question 9
a) Describe the role of d-orbitals in the formation of pi (π) bonds. [2]
b) In a molecule with a triple bond, how many sigma (σ) and pi (π) bonds are present? [2]
c) Why are molecules with resonance structures generally more stable than those that can be represented by a single Lewis structure? [3]
Question 10
a) Explain the concept of formal charge and its significance in drawing Lewis structures. [3]
b) For the molecule NO3^-, determine the formal charge on the nitrogen atom. [2]
c) How does the concept of resonance contribute to the stability of the NO3^- ion? [3]