AP Syllabus focus:
‘Hydraulic fracturing (fracking) can contaminate groundwater and release volatile organic compounds into the environment.’
Hydraulic fracturing is a drilling technique used to access oil and natural gas in low-permeability rock. Its key environmental concerns for AP Environmental Science are groundwater contamination risks and air pollution from VOC emissions.
What Fracking Is (and Why It Raises Environmental Concerns)
Core idea of the process
Fracking increases flow from tight rock by injecting a high-pressure mixture of water, sand, and chemicals to create and hold open fractures so hydrocarbons can move toward a well.
Hydraulic fracturing (fracking): A method of oil and gas extraction that injects high-pressure fluid into rock to create fractures, increasing permeability and releasing hydrocarbons.
Where impacts originate
Environmental impacts are concentrated at:
The well pad (drilling, pumping, storage tanks, compressors)
The subsurface wellbore (integrity of casing/cement)
The water and waste stream (flowback/produced water handling)
Groundwater Contamination Pathways
How fracking can contaminate groundwater
Groundwater contamination concerns focus on whether pollutants can reach aquifers used for drinking water. Major pathways include:
Well casing/cement failure: If steel casing or cement is poorly installed or degrades, fluids (or methane) can migrate into surrounding rock and potentially into groundwater.

This diagram shows a typical sequence of nested steel casing strings and cement in the upper portion of a gas well (not to scale). It highlights how multiple cemented barriers are designed to isolate groundwater-bearing zones from fluids moving inside the wellbore. Source
Surface spills and leaks: Chemicals, fuels, and wastewater can spill during transport, mixing, storage, or transfer; contaminants can infiltrate soil and percolate downward.
Wastewater mismanagement: Improper containment, illegal dumping, or failures in storage infrastructure can release contaminants that eventually reach groundwater.
What might contaminate groundwater
Potential contaminants associated with fracking operations include:
Salts (high TDS) from deep formation water
Hydrocarbons (e.g., petroleum compounds)
Fracturing additives (varies by site; can include surfactants, friction reducers, and biocides)
Metals and naturally occurring radioactive materials (NORM) that may be brought up in wastewater
Factors that influence risk
Risk is site-specific and depends on:
Depth and geology separating the target formation from aquifers
Well integrity (construction quality, maintenance, and monitoring)
Proximity of operations to recharge zones, faults, and private wells
Frequency and volume of chemical and wastewater handling at the surface
VOC Emissions and Air-Quality Impacts
What VOCs are and why they matter
Fracking operations can release volatile organic compounds (VOCs) from:
Flowback and produced water (evaporation from tanks and impoundments)
Pneumatic devices, valves, and fittings (leaks during operation)
Venting and flaring during well completion and maintenance
Truck traffic and diesel engines supporting the site
VOCs matter because they:
Contribute to ground-level ozone (smog) formation when reacting with nitrogen oxides in sunlight
Include compounds with direct health concerns (some VOCs are toxic at elevated exposure)
When emissions can be highest
Emissions can spike during:
Well completion (early production period when flowback is highest)
Equipment start-up/shutdown events
Periods of heavy truck traffic and on-site processing
Pollution Prevention and Risk Reduction (Conceptual)
Practices that reduce groundwater risk
Common protective approaches include:
Multiple casing strings and cementing to isolate aquifers
Pressure testing and integrity monitoring to detect leaks early
Secondary containment for tanks and chemical storage
Careful wastewater handling and documented chain-of-custody procedures
Practices that reduce VOC releases
Emission-reduction approaches include:
Leak detection and repair (LDAR) programs for components that commonly leak
Vapour recovery on tanks
Reduced venting during completion (capturing gas rather than releasing it)
Key Trade-offs to Keep in View
Fracking can increase domestic energy supplies, but AP Environmental Science emphasises that it can:
Contaminate groundwater through well integrity failures and surface/wastewater releases
Release VOCs that degrade air quality and contribute to smog formation
FAQ
They commonly use baseline sampling before drilling and repeat sampling afterwards.
They may also compare:
Changes in ion ratios, dissolved gases, and specific tracers over time
Patterns across multiple nearby wells to identify local versus regional sources
Green completions capture gases and vapours during well completion rather than releasing them.
This can reduce:
VOC emissions from early flowback
Losses of saleable hydrocarbons to the atmosphere
Setbacks aim to reduce exposure and risk from routine operations and accidents.
They help by increasing distance from:
Noise and air emissions
Potential spill zones
Heavy lorry traffic corridors
Key differences are whether wastewater is:
Stored in open versus closed systems
Treated to appropriate standards before discharge
Transported frequently (increasing spill probability) versus managed on-site under strict containment
Temperature and sunlight can increase VOC evaporation and speed ozone formation.
Wind and atmospheric inversions can also:
Concentrate pollutants locally
Transport VOCs and ozone downwind to other communities
Practice Questions
Explain one way hydraulic fracturing can lead to groundwater contamination. (2 marks)
Identifies a valid pathway (e.g., casing/cement failure or surface spill reaching soil/aquifer). (1)
Explains mechanism linking pathway to groundwater contamination (e.g., migration into aquifer, percolation through soil). (1)
Hydraulic fracturing sites can release VOCs. Describe two sources of VOC emissions at fracking sites and explain one environmental impact of these VOCs. (5 marks)
Describes first valid source (e.g., evaporation from flowback/produced-water tanks/impoundments). (1)
Describes second valid source (e.g., leaks from valves/fittings/pneumatic devices, venting during completion). (1)
Links VOCs to ground-level ozone formation (photochemical smog) with appropriate explanation. (2)
States one relevant environmental or health impact of ozone/VOCs (e.g., respiratory irritation, reduced crop productivity, degraded air quality). (1)
