AP Syllabus focus:
‘Most solid waste is disposed of in landfills. Landfills can contaminate groundwater through leachate and can release harmful gases during decomposition.’
Landfills are the dominant destination for municipal solid waste in the United States. Understanding their benefits and environmental risks helps explain why careful siting, management, and monitoring are essential.
What landfills do (and why they are used)
Landfills are designated sites where solid waste is concentrated for long-term disposal. Their continued use reflects practical benefits:
High capacity: Landfills can accept large volumes of mixed waste over long time periods.
Centralised containment: Waste is confined to a defined area rather than scattered across the landscape, reducing widespread litter and direct contact hazards.
Lower immediate cost: Compared with many alternative disposal methods, landfilling is often less expensive per tonne in the short term.
Land reuse potential (long term): Once filled and closed, some sites can be converted to limited-use spaces (for example, open space), though this depends on settlement and gas management.
These benefits explain why most solid waste is disposed of in landfills, even as communities also pursue reduction and diversion strategies.
Environmental risks: groundwater contamination from leachate
A core environmental concern is that landfills can contaminate groundwater through leachate.
Leachate: Liquid that forms as water percolates through waste, dissolving or carrying contaminants into a moving fluid.
Leachate forms when precipitation, surface runoff, or moisture already in the trash moves through the landfill. The resulting liquid can contain:
Dissolved organic matter that increases oxygen demand if it reaches surface waters
Inorganic ions and salts
Toxic substances depending on what was discarded (e.g., household chemicals)
Groundwater is especially vulnerable when landfills are placed over permeable soils, near a high water table, or where cracks and preferential flow paths allow faster downward movement.

Hydrogeologic cross-section illustrating how infiltration through refuse can create a local water-table mound beneath a landfill and drive leachate movement outward and downward. The figure highlights that groundwater flow patterns (not just the presence of contaminants) control where pollution travels and where it may emerge as springs or seepage. This provides a mechanistic explanation for why landfill siting and long-term groundwater monitoring are critical. Source
Because groundwater can move slowly, contamination may persist for years and spread beyond the landfill boundary before it is detected.

Conceptual cross-section of a landfill-related groundwater contamination plume, with contour lines representing decreasing contaminant concentration away from the source. It illustrates how leachate-driven contamination migrates with groundwater flow and can extend well beyond the landfill footprint. This kind of diagram helps explain why monitoring wells must be placed downgradient to track plume movement over time. Source
Why groundwater impacts matter
Groundwater pollution is difficult to reverse because contaminants can:
Disperse through an aquifer and reach private wells
Require costly treatment or replacement water supplies
Create long-lasting plumes that demand monitoring over decades
Environmental risks: harmful gases released during decomposition
Landfills can also release harmful gases during decomposition.

Flowchart showing the major components of a basic landfill gas (LFG) system: gas extraction from the waste mass (via wells and piping), movement of gas with blowers/vacuum, and routing to control devices such as a flare or to beneficial-use treatment. It connects the biology (anaerobic decomposition generating methane) to the engineered controls used to reduce explosion hazards and greenhouse-gas emissions. The diagram also emphasizes that “collection” and “treatment/use” are separate steps in managing landfill methane. Source
As buried waste breaks down, microbes generate gases whose composition depends on oxygen availability. In deeper, oxygen-poor zones, decomposition tends to be anaerobic and produces significant methane along with carbon dioxide and trace gases.
Methane (CH₄): A potent greenhouse gas produced during anaerobic decomposition of organic waste; it is also highly flammable.
Even when methane is the most discussed gas, landfill emissions can include:
Volatile organic compounds (VOCs) that contribute to odours and may pose health risks
Hydrogen sulfide and other reduced sulfur compounds associated with strong odours
Carbon dioxide (CO₂), a greenhouse gas that also contributes to asphyxiation risk in confined spaces
Why gas emissions are an environmental and safety issue
Climate forcing: Methane has much higher heat-trapping ability than CO₂ over short time scales, so uncontrolled releases increase climate impact.
Fire and explosion hazards: Methane can migrate and accumulate, creating flammability risks.
Local air quality and nuisance impacts: Odours and certain trace emissions can affect nearby communities.
Additional environmental concerns closely tied to landfill operation
While leachate and gas are the headline risks in AP Environmental Science, landfills can also create secondary impacts:
Habitat loss and fragmentation from land conversion
Vectors and pests (e.g., rodents, insects, scavenging birds) if waste is exposed
Noise, traffic, and dust from hauling and daily operations
Settling and subsidence as materials compact and decompose, complicating future land use
Key takeaways for AP Environmental Science
Landfills provide a central, high-capacity disposal option, which is why they remain widely used.
The major environmental risks are groundwater contamination via leachate and air impacts from decomposition gases, especially methane.
These risks make site selection and long-term monitoring critical parts of landfill management.
FAQ
Operators sample gas from wells or probes and analyse it with gas chromatography.
Typical components include:
$CH_4$ and $CO_2$ as the main gases
Trace VOCs (e.g., solvents)
Reduced sulfur compounds (e.g., hydrogen sulfide) linked to odours
Early on, readily degradable organics break down quickly, often producing stronger leachate and rising gas generation.
Over time:
Organic material becomes less reactive
Gas rates tend to decline
Leachate chemistry can shift as decomposition stages change
Higher risk is associated with:
Permeable soils or fractured rock
Shallow water tables
High rainfall (more percolation)
Locations near wells or recharge zones
These conditions increase the likelihood that leachate migrates into aquifers.
Often decades, because:
Waste continues decomposing slowly, producing gas
Leachate can still form when water enters
Settlement can damage covers and increase infiltration
This is why long-term monitoring and maintenance plans are commonly required.
Indicators can include:
New odour complaints downwind
Vegetation stress in localised patches (from gas migration)
Changes in nearby well water taste/odour
Elevated conductivity or specific contaminants detected in monitoring samples
Practice Questions
State what leachate is and explain one way it can harm groundwater near a landfill. (2 marks)
1 mark: Correct definition/description of leachate (contaminated liquid formed as water percolates through waste).
1 mark: One valid harm explained (e.g., carries dissolved contaminants into aquifers/drinking wells; creates a pollution plume).
Describe two benefits of using landfills for solid waste and explain three environmental risks associated with landfills, including at least one risk linked to decomposition. (5 marks)
Benefits (2 marks total):
1 mark each for two correct benefits (e.g., high-capacity disposal; concentrates waste in one controlled location; relatively low cost).
Risks (3 marks total):
1 mark: Leachate can contaminate groundwater.
1 mark: Decomposition can release harmful gases such as (greenhouse gas and/or flammability risk).
1 mark: One additional valid risk explained (e.g., odours/VOCs affecting local air quality; pest attraction; habitat loss due to land conversion).
