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AP Environmental Science Study Notes

9.7.3 Human activities that increase CO2 and drive acidification

AP Syllabus focus:

‘Activities that raise atmospheric CO2—burning fossil fuels, vehicle emissions, and deforestation—contribute to ocean acidification.’

Human actions are increasing atmospheric carbon dioxide (CO2), strengthening the flow of CO2 into seawater. This shift is a major human driver of ocean acidification, with especially strong links to energy use, transportation, and land-use change.

How human CO2 emissions connect to ocean acidification

The ocean and atmosphere continuously exchange CO2. When people add extra CO2 to the air, more CO2 tends to enter the ocean, increasing acidity.

Ocean acidification: A human-driven decrease in seawater pH caused primarily by the ocean’s uptake of excess atmospheric CO2.

A simplified chemistry pathway shows why added CO2 increases acidity in seawater.

Pasted image

Diagram of the overall seawater carbonate reaction pathway associated with ocean acidification, highlighting how dissolved CO2CO_2 and water drive reactions that consume carbonate ions (CO32CO_3^{2-}) and produce bicarbonate (HCO3HCO_3^-). This helps explain why rising atmospheric CO2CO_2 ultimately shifts seawater chemistry in ways that increase acidity and reduce carbonate availability for calcifying organisms. Source

CO2(g)CO2(aq) \mathrm{CO_2(g) \rightleftharpoons CO_2(aq)}

CO2(g) \mathrm{CO_2(g)} = Carbon dioxide in the atmosphere

CO2(aq) \mathrm{CO_2(aq)} = Dissolved carbon dioxide in seawater

CO2(aq)+H2OH2CO3H++HCO3 \mathrm{CO_2(aq) + H_2O \rightleftharpoons H_2CO_3 \rightleftharpoons H^+ + HCO_3^-}

H+ \mathrm{H^+} = Hydrogen ion that increases acidity (no unit requirement at AP level)

The key idea is that human activities that raise atmospheric CO2 increase dissolved CO2 in seawater, which increases hydrogen ions (H⁺) and lowers pH.

Human activities that increase atmospheric CO2

The specification emphasizes three major human drivers: burning fossil fuels, vehicle emissions, and deforestation.

Burning fossil fuels (power and heat)

Most anthropogenic CO2 comes from the combustion of coal, oil, and natural gas for electricity generation, industrial heat, and building energy.

  • Fossil fuels store carbon from ancient biomass; combustion rapidly transfers that carbon to the atmosphere as CO2.

  • Large point sources (for example, power plants) can produce sustained, high-volume emissions that accumulate in the atmosphere over time.

  • Higher energy demand typically increases total CO2 emissions unless energy systems shift to low-carbon sources.

Vehicle emissions (transportation)

Transportation is a direct, widespread source of CO2 due to fuel combustion in engines.

  • Cars, trucks, ships, and airplanes oxidize carbon in gasoline, diesel, or jet fuel into CO2.

  • Emissions are geographically dispersed but collectively large, especially in regions with high vehicle miles traveled.

  • Traffic congestion and inefficient driving conditions can increase fuel consumption per mile, raising CO2 output for the same transport service.

Deforestation and land-use change

Deforestation contributes to higher atmospheric CO2 in two connected ways: it releases stored carbon and reduces future carbon uptake.

  • Clearing and burning forests converts carbon in wood and soils into CO2 (and sometimes other carbon-containing gases).

  • Decomposition of cut vegetation also releases CO2 over time, even without burning.

  • Loss of trees reduces photosynthesis, weakening a major biological pathway that removes CO2 from the atmosphere.

  • Converting forests to agriculture or development often reduces long-term carbon storage in biomass and can disturb soils, further increasing CO2 release.

Why these activities matter for acidification (cause-and-effect chain)

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Timeline schematic connecting industrial-era CO2CO_2 emissions to ocean uptake and the chemical steps that generate H+H^+ and lower seawater pH. The figure visually reinforces the cause-and-effect chain in the notes by showing how increasing atmospheric CO2CO_2 corresponds with progressively lower ocean pH and increasing stress on marine ecosystems. Source

Human activities raise atmospheric CO2, and the ocean responds by absorbing a significant portion of that excess CO2.

  • More atmospheric CO2 → more CO2 dissolves into surface waters

  • More dissolved CO2 → more H⁺ produced in seawater

  • More H⁺ → lower pH (more acidic conditions)

Because the emission sources above are ongoing and globally widespread, they create a long-term pressure toward continued CO2 accumulation and continued ocean uptake, driving acidification.

FAQ

They combine fuel-sales data, traffic counts, and facility-reported fuel use with emissions factors.

They also use atmospheric measurements and modelling to attribute signals to transport corridors versus point sources.

$CO_2$ mixes globally in the atmosphere over time, so emissions are not confined to where they are produced.

Ocean uptake occurs across basins, so added atmospheric $CO_2$ can drive acidification in distant marine regions.

If fires are human-caused or linked to human land clearing, they effectively function as land-use emissions.

Natural fires can still emit $CO_2$, but the specification focus is on human activities that raise atmospheric $CO_2$.

Per unit energy, coal generally emits more $CO_2$ than oil, and oil more than natural gas.

Actual emissions also depend on plant efficiency and how the fuel is extracted and processed.

  • Stricter fuel-economy/efficiency standards

  • Electrification with low-carbon electricity

  • Low-carbon fuel standards that cut lifecycle $CO_2$

Practice Questions

State two human activities that increase atmospheric CO2CO_2 and contribute to ocean acidification. (2 marks)

  • Burning fossil fuels (1)

  • Vehicle emissions/transport fuel combustion (1)

  • Deforestation/land clearing (1)

  • (Any two)

Explain how deforestation can increase atmospheric CO2CO_2 and link this to ocean acidification. (5 marks)

  • Deforestation releases stored carbon as CO2CO_2 through burning (1)

  • Deforestation releases CO2CO_2 through decomposition of cleared biomass (1)

  • Fewer trees reduces photosynthesis/carbon uptake (1)

  • Higher atmospheric CO2CO_2 increases transfer/dissolution of CO2CO_2 into the ocean (1)

  • Dissolved CO2CO_2 increases H+H^+, lowering pH (acidification) (1)

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