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AP Biology Notes

3.4.5 Electron Transport and Proton Gradients in Chloroplasts

AP Syllabus focus:

‘Electron transfer through the thylakoid electron transport chain creates a proton gradient across the thylakoid membrane.’

Electron transport in chloroplast thylakoid membranes converts light-driven electron movement into a transmembrane proton (H⁺) gradient. This gradient stores potential energy by separating charge and pH between the thylakoid lumen and stroma.

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Practice Questions

FAQ

It uses plastoquinone/plastoquinol chemistry to move more H⁺ into the lumen per pair of electrons.

This can increase the H⁺ gain beyond simple electron hand-offs between carriers.

Researchers can track pH-sensitive dyes or observe electrochromic shifts in thylakoid pigments.

These signals change as membrane potential and lumenal acidity change.

Counter-ion movements (e.g., $Cl^-$ flux) and buffering in the lumen can reduce excessive charge separation.

This allows a strong $\Delta pH$ to persist.

Greater H⁺ permeability dissipates the gradient, so less energy is stored as a proton difference.

Electron transfer may continue, but the gradient-dependent energy capture is reduced.

It routes electrons back to the PQ/cytochrome b6f segment, increasing H⁺ accumulation via b6f without producing NADPH.

This can steepen the gradient when extra proton-driving force is needed.

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